In the bowl of a stand mixer (or just a large bowl if you're using a hand mixer), combine flour, sugar, cocoa, baking soda, baking powder, and salt. Mix on low until fully blended.
In a separate bowl, combine eggs, sour cream, vegetable oil, and vanilla.
With mixer on, pour liquid into dry ingredients and mix gently until smooth. Slowly pour in hot/warm coffee while mixer continues.
Pour an even amount of batter into three prepared cake pans (wax/parchment and shortening or other method as preferred). Bake at 300°F for about 30 minutes or until a toothpick comes out clean. Cool cakes for about 5 minutes after removing from the oven. Run a plastic knife quickly around the edges of each cake pan to help release the cake.
Turn the first cake layer onto a parchment paper covered plate. (Trim any dome off of the cake so layers will stack without cracking.) Do this with the second cake layer and stack parchment/cake on top of first layer. Do the same with the third layer and cover cake with cake carrier lid until cool. Then refrigerate until ready to assemble Smore's Cake.